OPTIMIZATION OF BLEND OF POLYMETHYL METHACRYLATE (PMMA) WITH POLY VINYLIDENE CHLORIDE-CO-ACRYLONITRILE (PVdC-co-AN) COMPOSITE ELECTROLYTES

Authors

  • M.Shanthia 120, Energy Materials Lab, Department of Physics, Alagappa University, Karaikudi-630003. Tamil Nadu, India
  • R.Subadevi 120, Energy Materials Lab, Department of Physics, Alagappa University, Karaikudi-630003. Tamil Nadu, India
  • M.Ramachandran 120, Energy Materials Lab, Department of Physics, Alagappa University, Karaikudi-630003. Tamil Nadu, India.
  • M.Sivakumar 120, Energy Materials Lab, Department of Physics, Alagappa University, Karaikudi-630003. Tamil Nadu, India
  • M.Shanthi Department of Physics, Kamaraj College of Engg. And Tech, Virudhunagar 626001, Tamil Nadu, India
  • M.Ramachandran Department of Physics, Arumugam Pillai SeethaiAmmal College, Tiruppathur-630 211, Tamil Nadu, India

Keywords:

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Abstract

A novel polymer electrolyte membranes are prepared bycomprising of poly (vinylidene chloride -co-acrylonitrile)
(PVdC-AN), poly (methylmethacrylate) (PMMA) with different ratio, with constant ratio of lithium per chlorate (LiClO4), and
Zirconia (ZrO2) by solution cast technique. The formation of blend polymer electrolyte complex has been confirmed by XRD
and FTIR spectroscopy analysis. The ac impedance studies are carried out to depict role of blendingof polymers on
conductivity. The high ionic conductivity of 0.6 x 10-4
at 303K has been observed for the blend ratio 25:75 of PVdCAN:PMMA. The temperature dependence of the blend polymer electrolyte is found to obey VTF relation. TG/DTA analysis
has been performed in order to investigate the thermal stability of the blend polymer electrolyte. The three dimensional
topographical image of the blend are investigated using AFM.

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Published

2022-08-23

Issue

Vol. 4 No. 17 (2017): NCN-2017 (National Conference On Nanomaterials)

Section

Articles

How to Cite

OPTIMIZATION OF BLEND OF POLYMETHYL METHACRYLATE (PMMA) WITH POLY VINYLIDENE CHLORIDE-CO-ACRYLONITRILE (PVdC-co-AN) COMPOSITE ELECTROLYTES. (2022). International Journal of Advance Engineering and Research Development (IJAERD), 4(17), -. https://www.ijaerd.org/index.php/IJAERD/article/view/6202

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